Organic compound/metal oxide hybrid thin film prepared by the liquid phase deposition method

• DEKI Shigehito

  Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University

• KODAMA Yasuaki

  Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University

• MIZUHATA Minoru

  Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University

抄録

Organic compound/metal oxide composite thin films have been prepared by the liquid-phase deposition method in a one-step deposition technique. Organic dyes were added to the metal fluoro-complexes aqueous solution in order to entrap these dyes within the growing thin films of metal oxides, yielding organic dye/metal oxide hybrid materials. According to Raman spectroscopy and X-ray photoelectron spectroscopy, the formation of the materials in the case of cationic dyes can be explained by the electrostatic interaction between negative charge density at the fluorinated surface of metal oxides and the cationic dyes. UV-Vis results indicate that stilbazo and pyrocatechol violet (catecholate dye molecules) form a charge transfer complex with metal oxides through the catechol moiety with a bidentate linkage.

収録刊行物

• Journal of the Ceramic Society of Japan

  Journal of the Ceramic Society of Japan 117 (1363), 326-329, 2009

  公益社団法人 日本セラミックス協会

キーワード

• Organic
• Metal oxide
• Composite
• Thin film
• Hybrid
• Liquid phase deposition

詳細情報

• CRID: 1390282680259352832
• NII論文ID: 110007123881
• NII書誌ID: AA12229489
• DOI: 10.2109/jcersj2.117.326
• ISSN: 13486535
• ISSN: 18820743
• NDL書誌ID: 10163661
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10163661
• Web Site: http://www.jstage.jst.go.jp/article/jcersj2/117/1363/117_1363_326/_pdf
• 本文言語コード: en
• データソース種別:
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  • NDL
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