水-岩石相互作用の生成物としてのアルリカ性鉱泉水

書誌事項

タイトル別名
  • Alkaline spring waters as a product of water-rock interaction
  • 水-岩石相互作用の生成物としてのアルカリ性鉱泉水
  • ミズ ガンセキ ソウゴ サヨウ ノ セイセイブツ トシテノ アルカリセイコウ

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This paper describes the chemistry of alkaline spring waters from the Abukuma mountain area, Fukushima Prefecture. The waters are formed by reaction of rainwater with felsic rocks under a limited CO2 supply. The data are plotted on a log (aCa2+/a2H+)-logaSiO<sub>2</sub> diagram (Fig. 1). Most of samples are located in a small area on the diagram. The waters having a pH higher than 9 are shown to be saturated with respect to calcite, thus suggesting that the alkaline waters represent an equilibrium product of water-felsic rock interaction. Assuming that the waters are in equilibrium with kaolinite-Ca-montmorillonite assemblage, the equilibrium constant for reaction (1) (see text) is estimated to be -11 as pK. However the chemistry of these waters cannot be fully explained by the system kaolinite-Ca-montmorillonite-aqueous solution. An additional Ca mineral, possibly Ca-zeolite, should be included in the system.

収録刊行物

  • 地球化学

    地球化学 16 (1), 25-29, 1982

    一般社団法人日本地球化学会

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