Mechanistic Aspects of Bioluminescence and Chemiluminescence(By a grant Reserch Institute for Integrated Science, Kanagawa University)

• Matsumoto, Masakatsu

• 松本, 正勝

• Ohashi, Mamoru

• 大橋, 守

• Watanabe, Nobuko

• 渡辺, 信子

• Fujimori, Ken

• 藤森, 憲

抄録

Bicyclic dioxetane bearing a (3-cyanoethenyl) phenyl group was found to be triggered by the Michael addition of a malonate anion with an accompanying emission of red light. 3-Adamantylidene-4-methoxy-1,2-dioxetanes bearing a 4-(3-hydroxy)phenyl substituted with a podand-type group, namely, 1,4,7-trioxaoctyl, 1,4,7,10-tetraoxaundecyl, or 1,4,7,10,13 -pentaoxa- tetradecyl were synthesized and their base-induced chemiluminescent decomposition was examined in an aqueous system. Optically active dioxetanes bearing a naphthylnaphthol moiety were also synthesized. They exhibited chemilumines" cence in molecular recognition.

収録刊行物

• Science Journal of Kanagawa University

  Science Journal of Kanagawa University 16 83-85, 2005-05-25

  神奈川大学

キーワード

• dioxetane
• chemiluminescence
• Michael addition
• molecular recognition

詳細情報

• CRID: 1050282677547355008
• NII論文ID: 120002111513
• NII書誌ID: AA12068302
• ISSN: 18800483
• HANDLE: 10487/1421
• Web Site: https://kanagawa-u.repo.nii.ac.jp/records/6907
• 本文言語コード: ja
• 資料種別: departmental bulletin paper
• データソース種別:
  • IRDB
  • CiNii Articles