Electrochemistry of Redox Reaction III. On the Kinetic Equations for Chronoamperometry

• Ohzuku Tsutomu

• Hirai Taketsugu

抄録

A basic kinetic equation of potential-step chronoamperometric current-time curve controlled by the rates of diffusion and electron transfer for a simple one-electron charge transfer reaction was given and various features of current-time curves were deduced from a theoretical treatment. The current-time equations for reversible and irreversible electron transfer processes appear as special cases with limited conditions of the equation reported in the present paper. And a potential-step chronoamperometric method to determine kinetic parameters from a current-time curve was proposed therefrom. The extension of a basic kinetic equation to more general multistep charge-transfer process was also considered.

収録刊行物

• Memoirs of the School of Engineering, Okayama University

  Memoirs of the School of Engineering, Okayama University 18 (1), 75-89, 1984-03-30

  岡山大学工学部

詳細情報

• CRID: 1390009224548240768
• NII論文ID: 120002307131
• NII書誌ID: AA00733903
• ISSN: 04750071
• DOI: 10.18926/15771
• Web Site: https://ousar.lib.okayama-u.ac.jp/15771
• 本文言語コード: en
• データソース種別:
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  • IRDB
  • CiNii Articles