Condensation of Ketones and t-Butyl Chloroacetate in the Presence of Magnesium.

• Moriwake Tosio

抄録

Condensation of σt -butyl chloroacetate and ketones by means of magnesium in ether or benzene alone was carried out but the excellent yields of P-hydroxy ester could not be obtained, and the results of the condensation of t -butyl bromoacetate and ketones by means of magnesium and mercuric chloride in benzene were also disappointing. When a mixture of benzene and ether was used as solvent in the condensation of t-butyl chloroacetate and ketone in the presence of magnesium and mercuric chloride, the yields of p-hydroxy esters from cyclohexanone and methyl isobutyl ketone were 62 and 71 % respectively, and were comparable with those of other condensing methods.

収録刊行物

• Memoirs of the School of Engineering, Okayama University

  Memoirs of the School of Engineering, Okayama University 1 (1), 51-53, 1966-03-31

  岡山大学工学部

詳細情報

• CRID: 1390009224548190208
• NII論文ID: 120002307140
• NII書誌ID: AA00733903
• ISSN: 04750071
• DOI: 10.18926/15545
• Web Site: https://ousar.lib.okayama-u.ac.jp/15545
• 本文言語コード: en
• データソース種別:
  • JaLC
  • IRDB
  • CiNii Articles