Synthetic studies of salinosporamide A through the intramolecular hydroamidation of alkynes
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Rhodium-catalyzed intramolecular hydroamidation of alkynes was carried out to construct the synthetic intermediates of a proteasome inhibitor, salinosporamide A. Several alkynyl formamides were synthesized and subjected to the hydroamidation reaction. Some derivatives with a methoxymethyl (MOM) or 2-methoxy-2-propyl (MOP) group near the reaction site were converted to the corresponding lactams in excellent yields.
収録刊行物
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- Journal of Organometallic Chemistry
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Journal of Organometallic Chemistry 696 (1), 42-45, 2011-01
Elsevier BV
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詳細情報 詳細情報について
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- CRID
- 1050282677278147712
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- NII論文ID
- 120002709543
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- NII書誌ID
- AA00704122
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- ISSN
- 0022328X
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- HANDLE
- 2433/134562
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- IRDB
- CiNii Articles