4-Chloro-2′,4′,6′-triethylbenzophenone: a redetermination

• 高橋, 弘樹

抄録

The structure of the title compound [systematic name: (4-chlorophenyl)(2, 4, 6-trimethylphenyl)methanone], C19H21ClO, has been redetermined at 100 K. The redetermination is of significantly higher precision than the previous structure determination at 133 K and reveals disorder of the one of the o-ethyl groups [occupancy factors = 0.77 (1) and 0.23 (1)] that was not identified in the previous report [Takahashi & Ito (2010). CrystEngComm, 12, 1628-1634]. The C-C-C-C torsion angles of the major and minor disorder components of the ethyl group with respect to the attached benzene ring are -103.7 (2) and -172.0 (6)°, respectively. It is of interest that the title compound does not display a single-crystal-to-single-crystal polymorphic phase transition on cooling, as was observed for a closely related compound, a fact that can be attributed to the disorder in the ethyl group.

収録刊行物

• Acta Crystallographica Section E Structure Reports Online

  Acta Crystallographica Section E Structure Reports Online 67 (4), 2011-04

  International Union of Crystallography (IUCr)

詳細情報

• CRID: 1050001202301686272
• NII論文ID: 120003018169
• NII書誌ID: AA12097683
• ISSN: 16005368
• HANDLE: 2433/139915
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles