Sulfonamide-Type Monoanionic Bidentate Ligands as Possible Chelate Extractants for theCopper(II) Cation

• Kato, Chikako

• Sugisaka, Noriko

• Hirasawa, Eri

• Oshima, Shunichi

• Hirayama, Naoki

書誌事項

タイトル別名

• Sulfonamide type monoanionic bidentate ligands as possible chelate extractants for the copper 2 cation

抄録

To evaluate the possible use of sulfonamide-type monoanionic N,N --bidentate ligands as chelate extradants for divalent metal cations, we studied the chelate extraction behavior of copper(II) cation into chloroform with several N-C2-N- bidentate ligands having the p-toluenesulfonamido group as a model system. All of the four N-C 2-N- ligands studied showed quantitative extractability for copper(II) and the metal:ligand ratio in the extracted species was 1:2. Furthermore, the order of the extraction constants for copper(II) with the ligands suggests that the number of π-electrons in the N-C2-N - structure is an important factor in achieving high complexation ability and extractability.

収録刊行物

• Solvent Extraction Research and Development, Japan

  Solvent Extraction Research and Development, Japan 14 171-176, 2007-01-01

  Japan Association of Solvent Extraction = 日本溶媒抽出学会

詳細情報

• CRID: 1050564285895830272
• NII論文ID: 120005316313
• NII書誌ID: AA11114608
• ISSN: 13417215
• HANDLE: 2297/35243
• NDL書誌ID: 8832022
• Web Site: https://kanazawa-u.repo.nii.ac.jp/records/10617
• Web Site: http://id.ndl.go.jp/bib/8832022
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8832022
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • NDL
  • CiNii Articles