Prediction of liquid molar volumes at normal boiling points by additive method

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  • 加算法による標準沸点における 液体モル体積の推算
  • カサンホウ　ニヨル　ヒョウジュン　フッテン　ニオケル　エキタイ　モル　タイセキ　ノ　スイサン

Abstract

An additive method by Le Bas has been adopted to predict the liquid molar volumes at normal boiling points vb for pure substances. Its calculation procedure is reviewed in detail and results obtained are compared with the experimental vb data. It is acknowledged that the additive method can be applied with good performances to predict vb of various substances except small molecules such as acetone, methanol, ethanol and water.

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