Studies on Phase Change Characteristics of Binary Mixtures of Erythritol and MgCl2 6H2O
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- Kubota Mitsuhiro
- Department of Energy Engineering and Science, Nagoya University
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- Ona Erwin P.
- Department of Energy Engineering and Science, Nagoya University
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- Watanabe Fujio
- Research Institute for Industrial Technology, Aichi Institute of Technology
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- Matsuda Hitoki
- Department of Energy Engineering and Science, Nagoya University
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- Hidaka Hideto
- Mitsubishi Chemical Group Science and Technology Research Center, Inc.
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- Kakiuchi Hiroyuki
- Mitsubishi Chemical Group Science and Technology Research Center, Inc.
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This study investigated a novel idea of combining an organic component erythritol with an inorganic component MgCl2·6H2O to prepare new PCMs suitable for domestic water heating. A DSC analysis indicated that mixtures containing less than 20 wt% MgCl2·6H2O have melting temperatures above 353 K and latent heat values greater than 120 kJ/kg. Thermal cycling of erythritol-based PCMs in test tubes showed good stability in terms of nucleation temperature. However, the erythritol-based PCMs were found to undergo supercooling of about 50 K below the melting temperature, similar to erythritol. An analysis of the distribution of the salt hydrate component in the solid phase in a scale-up experiment revealed the salt hydrate’s possibility of accumulating at the bottom of the unit. The effect of ultrasonic irradiation on prevention of component segregation was also demonstrated.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 40 (1), 80-84, 2007
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204568234752
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- NII論文ID
- 130000019137
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- NII書誌ID
- AA00709658
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 8612789
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可