Adsorption properties of high-silica zeolites for high-temperature chemical heat pumps.
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- Fujiwara Ichiro
- National Chemical Laboratory for Industry
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- Suzuki Kunio
- National Chemical Laboratory for Industry
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- Shin Shigemitsu
- National Chemical Laboratory for Industry
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- Sato Masahito
- National Chemical Laboratory for Industry
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To evaluate their usability as adsorbents in chemical heat pumps for high-temperature use (over 373 K), an accelerated aging test by steam was performed for various zeolites and the adsorption equilibria of selected zeolites were measured. from the high-temperature steaming test it was found that high-silica zeolites like Na-mordenite, USY (ultrastable Y) and HY had higher thermal stability than conventional A- or X-type zeolite. Further, measurements of isotherms of Na-mordenite and USY showed that they maintained adsorption capacity even at 473 K. Acquired isosters of each zeolite and water were approximated as straight lines in the range from room temperature to 473 K. On their charts, heat transformer (chemical heat pump) cycles that work at high temperatures could be generated. High-silica zeolites like Na-mordenite or USY are therefore expected to be usable as adsorbents of water for repeating chemical heat pump operations at high temperature, though their total adsorption capacities are smaller than those of A- or X-type zeolites.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 23 (6), 738-744, 1990
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679542740352
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- NII論文ID
- 130000021842
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- NII書誌ID
- AA00709658
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- COI
- 1:CAS:528:DyaK3MXmsFShug%3D%3D
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- ISSN
- 18811299
- 00219592
- http://id.crossref.org/issn/00219592
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可