Synthesis of D-Allose Fatty Acid Esters via Lipase-Catalyzed Regioselective Transesterification

• AFACH Ghanwa

  Department of Biochemistry and Food Science, Faculty of Agriculture, Kagawa University

• KAWANAMI Yasuhiro

  Department of Biochemistry and Food Science, Faculty of Agriculture, Kagawa University

• IZUMORI Ken

  Rare Sugar Research Center, Kagawa University

Bibliographic Information

Other Title

• Synthesis of<scp>D</scp>-Allose Fatty Acid Esters<i>via</i>Lipase-Catalyzed Regioselective Transesterification

Abstract

The acylation of the rare sugar, D-allose (the C-3 epimer of D-glucose), with fatty acid vinyl esters was successfully carried out using Candida antarctica lipase in acetonitrile at 45 °C to give D-allose 6-alkanoates with high regioselectivity in good yields.

Journal

• Bioscience, Biotechnology, and Biochemistry

  Bioscience, Biotechnology, and Biochemistry 69 (4), 833-835, 2005

  Japan Society for Bioscience, Biotechnology, and Agrochemistry

Keywords

• rare sugar
• sugar fatty acid ester
• <I>Candida antarctica</I> lipase
• <small>D</small>-allose

Details

• CRID: 1390282681452040192
• NII Article ID: 130000030368
• NII Book ID: AA10824164
• DOI: 10.1271/bbb.69.833
• ISSN: 13476947
• ISSN: 09168451
• NDL BIB ID: 7308363
• PubMed: 15849425
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7308363
• Web Site: http://www.tandfonline.com/doi/pdf/10.1271/bbb.69.833
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• Abstract License Flag: Disallowed