Botanical and Geographical Origin Identification of Industrial Ethanol by Stable Isotope Analyses of C, H, and O

• ISHIDA-FUJII Keiko

  R and D Center, Alcohol Enterprise Head Office, New Energy and Industrial Technology Development Organization

• GOTO Shingo

  R and D Center, Alcohol Enterprise Head Office, New Energy and Industrial Technology Development Organization

• UEMURA Ryu

  Department of Environmental Science and Technology, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology SORST Project, JST

• YAMADA Keita

  SORST Project, JST Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

• SATO Michikatsu

  R and D Center, Alcohol Enterprise Head Office, New Energy and Industrial Technology Development Organization

• YOSHIDA Naohiro

  Department of Environmental Science and Technology, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology SORST Project, JST Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology Frontier Collaborative Research Center, Tokyo Institute of Technology

抄録

The isotope ratios of carbon, hydrogen, and oxygen of rectified alcohols were determined to distinguish their botanical and geographical origins by continuous flow-isotope ratio mass spectrometry (CF-IRMS). The ¹³C/¹²C and ¹⁸O/¹⁶O ratios of 27 fermented alcohols with known origins showed clusters derived from each botanical origin, viz. corn, sugarcane, wheat, and tapioca. C3 and C4 plants were easily distinguishable by the ¹³C/¹²C ratio. Sugarcane and corn are both C4 plants, and they showed small differences in isotope ratios. The combination plots of the D/H and ¹⁸O/¹⁶O ratios enabled us to designate the geographical origins of alcohol derived from the same kind of crop, such as Chinese or American corn. The chemically synthetic and fermented alcohols were clearly distinguished by D/H and ¹⁸O/¹⁶O ratios. Isotope ratios were useful for origin identification of alcohol. We plan to construct a database of alcohol isotope ratios to determine the origins of raw materials in alcohol.

収録刊行物

• Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ

  Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ 69 (11), 2193-2199, 2005

  公益社団法人 日本農芸化学会

キーワード

• isotope ratio mass spectrometry
• ethanol
• origin identification

詳細情報

• CRID: 1390282681449453824
• NII論文ID: 130000030494
• NII書誌ID: AA10824164
• DOI: 10.1271/bbb.69.2193
• COI: 1:CAS:528:DC%2BD2MXhtlWnurvL
• ISSN: 13476947
• ISSN: 09168451
• NDL書誌ID: 7729181
• PubMed: 16306702
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7729181
• Web Site: http://www.tandfonline.com/doi/pdf/10.1271/bbb.69.2193
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可