湖沼堆積物中から抽出されたフルボ酸のXAD樹脂吸着による分画と錯化能力

書誌事項

タイトル別名
  • Fractionation of Fulvic Acid Extracted from Lake Sediments Using XAD Resins and the Metal Complexing Ability.
  • コショウ タイセイブツ チュウ カラ チュウシュツサレタ フルボサン ノ XAD ジュシ キュウチャク ニヨル ブンカク ト サクカ ノウリョク

抄録

Fulvic acid extracted from lake sediments was treated with Amberlite XAD-2 and XAD-8 resins. The metal complexing ability of the fulvic acid was measured at pH 6.0 with a Cu2+ titration method, in which free Cu2+ was determined with an ion selective electrode. A two binding site model, in which there are two kinds of the molecules having strong and weak complexing ability and they complex with metal ion at the ratio of 1 : 1, was employed for the determination of the stability constant and complexing capacity of the fulvic acid, because the hyperbolic approxmation could apply to the Scatchard plot of the found values.<br>The stability constants of the fulvic acids having strong complexing ability and weak complexing ability were in the range of 6.33-7.12 and 4.35-4.66, respectively. Both colorless fractions of the fulvic acid which were not adsorbed on XAD-2 and XAD-8 resins had such a high complexing ability as 44 and 32 μmol·g-1, respectively.<br>On the other hand, both colored fractions of the fulvic acid which were adsobed on the resins had only little complexing capacity.

収録刊行物

  • 水環境学会誌

    水環境学会誌 16 (10), 690-695, 1993

    公益社団法人 日本水環境学会

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