ゆらぎと回折実験　回折学と熱力学の接点

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タイトル別名
  • Fluctuations Obtained by Diffraction Experiments. Contact Point of Thermodynamics and Diffraction.
  • ユラギ ト カイセツ ジッケン カイセツガク ト ネツリキガク ノ セッテン
  • —Contact Point of Thermodynamics and Diffraction—
  • ―回折学と熱力学の接点―

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抄録

In order to reveal the mixing state of two-component liquids, a description of “fluctuation” is presented on behalf of the strucutre description by radial distribution functions. The concentration fluctuation and the Kirkwood-Buff parameters are the good parameters to investigate the mixing state. These parameters are obtained by small-angle X-ray scattering experiments. The theoritical base of the parameters is reviewed. As an example of the analysis of the mixing state, the small-angle X-ray scattering studies for ethyl alcohol-water, iso-propyl alcohol-water, n-propyl alcohol-water and tert-butyl alcohol-water are presented.

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