多成分不飽和脂肪酸の液液平衡についての一考察

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タイトル別名
  • A correlation of liquid-liquid equilibria for long-chain unsaturated fatty acids.
  • タセイブン フホウワ シボウサン ノ エキエキ ヘイコウ ニ ツイテ ノ イチ

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抄録

Liquid-liquid equilibria data for a system of n-heptane, acetonitrile (10 wt % water) and fatty acids (oleic, linoleic, linolenic) were experimentally investigated. A correlation method was proposed by taking account of association of fatty acids in each phase. In this correlation, the concentration of the i-component fatty acid in the acetonitrile phase, yi, is related to the concentration of solute in the pure i-component system, <BR>y°i, at the same concentration of total solutes in the n-heptane phase, χ, and the solvent-free mole fraction of the i-component in the n-heptane phase, Xi, as follows.<BR>yi=y°i Xi<BR>The experimental data were well correlated by this equation. In addition, y°i is given as a function of χ for each component mentioned above.

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