New synthetic method of hydroxyl-terminated telechelic polyacetals based on polyaddition of hydroxyalkyl vinyl ether in the presence of diol

• HASHIMOTO Tamotsu

  Department of Materials Science and Engineering, Faculty of Engineering, Fukui University

• UMEHARA Akihiro

  Department of Materials Science and Engineering, Faculty of Engineering, Fukui University

• ISHIZUKA Koji

  Department of Materials Science and Engineering, Faculty of Engineering, Fukui University

• KODAIRA Toshiyuki

  Department of Materials Science and Engineering, Faculty of Engineering, Fukui University

抄録

Hydroxyl-terminated telechelic polyacetals were synthesized by polyaddition of 4-hydroxybutyl vinyl ether (HBVE; CH₂=CH-O-CH₂CH₂CH₂CH₂-OH) in the presence of 1, 4-butanediol with p-toluenesulfonic acid monohydrate (TSAM) as a catalyst in tetrahydrofuran (THF) at 0°C. The structural analysis showed that the produced polymers had hydroxyl groups at both the chain ends. The polyacetals thus obtained were stable under neutral and basic conditions, but exhibited smooth degradation with treatment of acid to give 1, 4-butanediol in quantitative yield. The polymers were highly viscous liquid and its glass transition temperature (T_g) was -72°C.

収録刊行物

• Ｐｒｏｃｅｅｄｉｎｇｓ　ｏｆ　ｔｈｅ　Ｊａｐａｎ　Ａｃａｄｅｍｙ．　Ｓｅｒ．　Ｂ：　Ｐｈｙｓｉｃａｌ　ａｎｄ　Ｂｉｏｌｏｇｉｃａｌ　Ｓｃｉｅｎｃｅｓ

  Ｐｒｏｃｅｅｄｉｎｇｓ　ｏｆ　ｔｈｅ　Ｊａｐａｎ　Ａｃａｄｅｍｙ．　Ｓｅｒ．　Ｂ：　Ｐｈｙｓｉｃａｌ　ａｎｄ　Ｂｉｏｌｏｇｉｃａｌ　Ｓｃｉｅｎｃｅｓ 77 (4), 63-67, 2001

  日本学士院

キーワード

• Polyacetal
• telechelic polymer
• polyaddition
• vinyl ether
• hydroxyl group
• degradable polymers
• chemical recycling

詳細情報

• CRID: 1390001204145413376
• NII論文ID: 130000907950
• NII書誌ID: AA00785485
• DOI: 10.2183/pjab.77.63
• ISSN: 13492896
• ISSN: 03862208
• ISSN: http://id.crossref.org/issn/03862208
• NDL書誌ID: 5782232
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5782232
• Web Site: http://www.jstage.jst.go.jp/article/pjab1977/77/4/77_4_63/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可