Organic Sulfur Compounds. V. Reactions of Arylsulfonic Acids with Alkyl and Aryl Chlorosulfites

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<jats:title>Abstract</jats:title> <jats:p>Silver p-toluenesulfonate has been found to react with alkyl and aryl chlorosulfite to give p-toluenesulfonic esters. Mixed anhydrides of the sulfonic acid and monoalkyl or monoaryl sulfite were postulated as the intermediates. No rearrangement of the alkyl group was observed during the reaction. The reaction mechanism was studied by means of the 18O tracer technique.</jats:p>

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