Unusual Reductive Deamination of 2,6-Dibromo-3,4,5-trimethylaniline by Alkyl Nitrites in <i>N</i>,<i>N</i>-Dimethylformamide. Simultaneous Side-chain Nitration

• Hitomi Suzuki

  Department of Chemistry, Faculty of Science, Hiroshima University

• Tadashi Mishina

  Department of Chemistry, Faculty of Science, Hiroshima University

• Terukiyo Hanafusa

  Department of Chemistry, Faculty of Science, Hiroshima University

抄録

Treatment of 2,6-dibromo-3,4,5-trimethylaniline with t-butyl nitrite in N,N-dimethylformamide at 60–65 °C was found to give a significant amount of a side-chain nitration product, 3,5-dibromo-2,6-dimethylphenylnitromethane, in addition to the expected 4,6-dibromo-1,2,3-trimethylbenzene.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 51 (10), 3099-3100, 1978-10-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219100995328
• NII論文ID: 130001970140
• DOI: 10.1246/bcsj.51.3099
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/51/10/3099/56099021/bcsj.51.3099.pdf
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