The Liquid-phase Oxidation of Aldehydes with Fe,Cu-Poly-phthalocyanine and Cobalt Tetra-<i>p</i>-tolylporphyrin

• Yasukazu Ohkatsu

  Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo

• Osamu Sekiguchi

  Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo

• Tetsuo Osa

  Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo

抄録

The effect of chemical species in a reaction system on the oxidation reaction of aldehydes was studied using Fe,Cu-polyphthalocyanine and cobalt tetra-p-tolylporphyrin as catalysts. Both catalysts activated the oxygen molecule on their central metals and then abstracted the hydrogen atom from aldehydes to initiate autoxidation. In this initiation step, every chemical species present in the reaction system, such as the solvent, the aldehyde, the oxygen molecule and the catalyst, is found to have an effect, one after another, either to accelerate or to retard the rate of initiation. The correlation of the nature of chemical species with such mutual interaction was discussed in detail.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 50 (3), 701-705, 1977-03-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694077556352
• NII論文ID: 130001970664
• DOI: 10.1246/bcsj.50.701
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/50/3/701/56091364/bcsj.50.701.pdf
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