The Photochemical Sulfenylation of Hindered Phenols with Diaryl Disulfides

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<jats:title>Abstract</jats:title> <jats:p>The photochemical reaction of diaryl disulfides with 2,6-disubstituted phenols was investigated. The reaction with highly hindered phenols proceeded appreciably upon irradiation with a high-pressure mercury lamp, giving rise to 4-arylthio-2,6-disubstituted phenols. The reaction was initiated by the homolytic scission of the disulfides.</jats:p>

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