The Reaction of Disodium Tetracarbonylferrate(–II) with Aldehydes

• Masakazu Yamashita

  Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

• Yoshihisa Watanabe

  Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

• Take-aki Mitsudo

  Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

• Yoshinobu Takegami

  Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

抄録

Disodium tetracarbonylferrate (–II) is an efficient catalyst for the dismutation of aromatic aldehydes to esters, 2RCHO→RCOOCH2R. Aliphatic ones give aldol-condensation products upon treatment with the ferrate. A successive reaction of the ferrate with an aldehyde, RCHO, and then with alkyl iodide, R’I, gives an ester, R’COOCH2R, after protonation. The mechanisms of these reactions are discussed.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 49 (12), 3597-3600, 1976-12-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694077321216
• NII論文ID: 130001971650
• DOI: 10.1246/bcsj.49.3597
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/49/12/3597/56094510/bcsj.49.3597.pdf
• データソース種別:
  • Crossref
  • CiNii Articles