Charge-transfer and Proton-transfer in the Formation of Molecular Complexes. X. Picric Acid Complexes with 2,5-Dichloroaniline

• Yoshio Matsunaga

  Department of Chemistry, Faculty of Science, Hokkaido University

• Gunzi Saito

  Department of Chemistry, Faculty of Science, Hokkaido University

• Naoto Sakai

  Department of Chemistry, Faculty of Science, Hokkaido University

抄録

Yellow 2,5-dichloroanilinium picrate was found to isomerize into a red complex of the charge-transfer type at 74 °C with a heat of transition of 4.2 kcal/mol. In addition, a charge-transfer complex with a 1 : 3 mole ratio was isolated.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 47 (11), 2873-2874, 1974-11-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219100154496
• NII論文ID: 130001973688
• DOI: 10.1246/bcsj.47.2873
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/47/11/2873/56091704/bcsj.47.2873.pdf
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