The Crystal and Molecular Structure of Dimethyltin Chloride <i>N</i>,<i>N</i>-Dimethyldithiocarbamate

• Kenji Furue

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Toshihide Kimura

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Noritake Yasuoka

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Nobutami Kasai

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Masao Kakudo

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

The molecular structure of dimethyltin chloride N,N-dimethyldithiocarbamate, [(CH3)2-SnCl(S2CN(CH3)2)], has been determined from three-dimensional X-ray diffraction data. The unit-cell dimensions are a=12.67, b=7.64, c=12.11 Å, and β=110.3°. The space group is P21/c. Four formula units are contained in a unit-cell. The structure was established by the heavy-atom method. The coordination around the tin atom is a distorted trigonal bipyramid with the following bond distances: Sn–C, 2.17(5) and 2.20(5) Å, Sn–Cl, 2.46(1) Å and Sn–S, 2.48(1) and 2.79(1) Å. Two methyl groups are both in equatorial positions.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 43 (6), 1661-1667, 1970-06-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644029244032
• NII論文ID: 130001977145
• DOI: 10.1246/bcsj.43.1661
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/43/6/1661/55952281/bcsj.43.1661.pdf
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