Stereoselectivity in the Hydrogenation of 4-<i>t</i>-Butylcyclohexanone with Catalytically-Active Powder Electrodes
-
- Senda Yasuhisa
- Department of Chemistry, Faculty of Science, Yamagata University
-
- Tateoka Minako
- Department of Chemistry, Faculty of Science, Yamagata University
-
- Itoh Hiroki
- Department of Chemistry, Faculty of Science, Yamagata University
-
- Ishiyama Jun-ichi
- Department of Engineering Science, Faculty of Engineering, Tohoku University
書誌事項
- タイトル別名
-
- Stereoselectivity in the Hydrogenation of 4-t-Butylcyclohexanone with Catalytically-Active Powder Electrodes.
抄録
The electrocatalytic hydrogenation of the title compound was examined over Raney Ni, Raney Co, Pt-carbon and Pd-carbon as hydrogen-active powder electrodes. A high conversion of ketone to alcohol was observed on the Raney catalysts when the pKa values of the proton sources employed were around 5. The metal-on-carbon catalysts showed a relatively low conversion of ketone regardless of the proton sources. The stereochemistry of the reaction was examined.
収録刊行物
-
- Bulletin of the Chemical Society of Japan
-
Bulletin of the Chemical Society of Japan 64 (11), 3302-3305, 1991
公益社団法人 日本化学会
- Tweet
キーワード
詳細情報
-
- CRID
- 1390001204116608512
-
- NII論文ID
- 130001979306
-
- ISSN
- 13480634
- 00092673
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可