Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate. Highly lipophilic stable anionic agent for solvent-extraction of cations.

• Nishida Hiroshi

  Research Institute of Industrial Science, Kyushu University 86

• Takada Naoko

  Research Institute of Industrial Science, Kyushu University 86

• Yoshimura Masaji

  Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University 39

• Sonoda Takaaki

  Research Institute of Industrial Science, Kyushu University 86

• Kobayashi Hiroshi

  Research Institute of Industrial Science, Kyushu University 86

Abstract

Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB) anion was highly lipophilic, practically insoluble in water, and durable against acid and oxidants. Partition equilibria of alkali TFPB between water and organic solvents and the stability in acid media are described and compared with the properties of the parent tetraphenylborate and of some fluorine-containing homologues.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 57 (9), 2600-2604, 1984

  The Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1390001204121965696
• NII Article ID: 130001984126
• DOI: 10.1246/bcsj.57.2600
• COI: 1:CAS:528:DyaL2cXlslymtb4%3D
• ISSN: 13480634
• ISSN: 00092673
• ISSN: http://id.crossref.org/issn/00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/57/9/2600/55672241/bcsj.57.2600.pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed