Preparation and Characterization of Dichlorobis(<i>N</i>-alkylsalicylideneaminato)manganese(IV) Complexes

• Takayuki Matsushita

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yoshihisa Hirata

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Toshiyuki Shono

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

The chlorobis(N-alkylsalicylideneaminato)manganese(III) complexes, MnIII(N-Rsai)2Cl, react with hydrogen chloride to give the corresponding dichloromanganese(IV) complexes, MnIV(N-Rsai)2Cl2, as deep green crystals; R can be n-C3H7, n-C4H9, i-C4H9, n-C6H13, c-C6H11, n-C8H17, n-C12H25, n-C18H37, CH2C6H5, or CH2CH2C6H5. These complexes were characterized by the magnetic susceptibilities, electronic spectra, infrared spectra, and cyclic voltammograms. The complexes (R=n-C12H25 and n-C18H37) are found to be stable toward water in the solid state. A trans, six-coordinate configuration is proposed for these Mn(IV) complexes on the basis of the infrared spectra.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 55 (1), 108-112, 1982-01-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644031834880
• NII論文ID: 130001986808
• DOI: 10.1246/bcsj.55.108
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/55/1/108/55666603/bcsj.55.108.pdf
• データソース種別:
  • Crossref
  • CiNii Articles