Reactions of Bis(β-diketonato)palladium(II) and -platinum(II) with Tertiary Phosphines

• Seichi Okeya

  Faculty of Education, Wakayama University

• Yukio Nakamura

  Faculty of Science, Osaka City University

• Shinichi Kawaguchi

  Faculty of Science, Osaka City University

抄録

Bis(β-diketonato)palladium(II) and -platinum(II) readily react with tertiary phosphines (L) to afford [M(β-dik)(β-dik-O)L], [M(β-dik)L2](β-dik), [ML4](β-dik)2, [M(β-dik-O)2L2], and [M(β-dik)(β-dik-C)L] complexes, which were characterized mainly by infrared and 1H and 13C NMR spectroscopy. Factors influencing the relative stability of each bonding mode of β-diketonate anions were investigated.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 54 (11), 3396-3408, 1981-11-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644031762944
• NII論文ID: 130001987557
• DOI: 10.1246/bcsj.54.3396
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/54/11/3396/56105661/bcsj.54.3396.pdf
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