The <i>r</i>s Structures of Fluoromethyl, Chloromethyl Ethers, and Methyl 2-Propynyl Ether

• Michiro Hayashi

  Department of Chemistry, Faculty of Science, Hiroshima University

• Hiroshi Kato

  Department of Chemistry, Faculty of Science, Hiroshima University

抄録

18O enriched samples of chloromethyl methyl ether and chloromethyl ethyl ether were prepared and their microwave spectra were measured. The rS structures of fluoromethyl methyl ether, fluoromethyl ethyl ether, chloromethyl methyl ether, chloromethyl ethyl ether, and methyl 2-propynyl ether were re-evaluated from the observed rotational constants obtained under the common constraints and assumptions on the structures of the molecules. A comparison of the rS structures was made between the five molecules and between the molecules and their related molecules.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 53 (10), 2701-2710, 1980-10-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694078098816
• NII論文ID: 130001988346
• DOI: 10.1246/bcsj.53.2701
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/53/10/2701/56101283/bcsj.53.2701.pdf
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