多核金属錯体の核間π共役相互伜用と酸化還元電位

• 陳 競鳶

  Department of Chemistry, Faculty of Science, Kanazawa University

• 青木 幸一

  Department of Applied Physics, Fukui University

書誌事項

タイトル別名

• Redox potentials of polynuclear metal complexes by π-conjugated metal-interaction

抄録

Polynuclear metal complexes of which redox sites are connected with π-conjugated ligands take a number of mixed valence states. They exhibit several redox potentials owing to interaction between redox centers through the π-conjugated bridges. Questions arise about the definition of the interaction, a relation between the number of nuclei and the number of redox potentials, and a relationship between redox potentials and geometry of the complexes. This paper answers these questions thermodynamically as well as quantum mechanically. The interaction energy in this paper is defined as a pair energy between a reduced and an oxidized sites. Even this simplest definition generates complicated redox behaviors because of formation of various isomers when the number of metal centers increases.

収録刊行物

• Ｒｅｖｉｅｗ　ｏｆ　Ｐｏｌａｒｏｇｒａｐｈｙ

  Ｒｅｖｉｅｗ　ｏｆ　Ｐｏｌａｒｏｇｒａｐｈｙ 46 (2), 85-104, 2000

  日本ポーラログラフ学会

キーワード

• General Earth and Planetary Sciences
• General Environmental Science

詳細情報

• CRID: 1390001206572083456
• NII論文ID: 130002035633
• DOI: 10.5189/revpolarography.46.85
• ISSN: 18847692
• ISSN: 00346691
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可