ハロゲン化合物や有機酸塩を含浸させた木質原料の炭素化で得られる多孔性炭素材料の細孔特性

書誌事項

タイトル別名
  • Porosity of carbonaceous materials prepared by the carbonization of saw-dust impregnated with an aqueous solution of halide or organic acid salt

抄録

Saw-dust of Japanese cypress, which was often used as a raw material of activated carbon, impregnated with an aqueous solution of halide or organic acid salt was carbonized and the porosities of the carbonized samples were measured. When saw-dust impregnated with potassium or sodium iodide or bromide was carbonized at 800 °C, chemical activation occurred and the carbonized sample had a larger specific surface area than one prepared by normal carbonization without using inorganic compounds. However, no chemical activation was found in the case of magnesium halides and other metal chlorides. In experiments using acetates, potassium caused stronger chemical activation than sodium or magnesium. It was also found that chemical activation did not occur in carbonization at 600 °C and that the chemical activation occurred at a higher carbonization temperature than the melting point of the inorganic compound used. It is therefore believed that the reactivity of the inorganic compound, such as its corrosion of the carbonaceous solid, is intensified by using a higher carbonization temperature than its melting point in order to promote the chemical activation.

収録刊行物

  • 炭素

    炭素 2014 (261), 8-13, 2014

    炭素材料学会

被引用文献 (1)*注記

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参考文献 (8)*注記

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詳細情報 詳細情報について

  • CRID
    1390001204229186432
  • NII論文ID
    130003395588
  • DOI
    10.7209/tanso.2014.8
  • ISSN
    18845495
    03715345
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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