Morphology and Nanostructure of Granular Materials Built from Nanoparticles
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- Castillo Jose L.
- Departamento de Fisica Matematica y de Fluidos, Facultad de Ciencias, UNED
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- Martin Santiago
- Departamento de Fisica Matematica y de Fluidos, Facultad de Ciencias, UNED
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- Rodriguez-Perez Daniel
- Departamento de Fisica Matematica y de Fluidos, Facultad de Ciencias, UNED
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- Perea Alvaro
- Departamento de Fisica Matematica y de Fluidos, Facultad de Ciencias, UNED
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- Garcia-Ybarra Pedro L.
- Departamento de Fisica Matematica y de Fluidos, Facultad de Ciencias, UNED
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Nanopowders or nanoparticles can be used as building blocks for the preparationof new materials with a prescribed structure. Monte Carlo simulations have shownthat the morphological properties (bulk porosity and surface roughness) of agranular deposit can be tailored by properly adjusting the velocity of theparticles approaching the deposit. Based on these theoretical predictions,experiments have been conducted to prepare nanostructured materials from carbonnanoparticles. By electrohydrodynamic atomization of a liquid suspension (carbonnanoparticles dispersed in ethanol), an electrospray of small droplets isgenerated. The charged droplets are driven by the electric field with theethanol evaporating along the droplet path, leaving dry nanoparticles thatdeposit on the collecting surface. The surface roughness of the resultingmaterial has been characterized as a function of the voltage drop. Moreover,catalytic suspensions of platinum supported on carbon nanoparticles (Pt/C) inNafion®-alcohol solutions have been electrosprayed overcarbon paper to prepare electrodes for proton exchange membrane fuel cells(PEMFC). The fuel cell power density was measured as a function of the platinumloading and the range of parameters leading to optimal platinum utilization wasobtained.
収録刊行物
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- KONA Powder and Particle Journal
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KONA Powder and Particle Journal 31 (0), 214-233, 2014
公益財団法人 ホソカワ粉体工学振興財団
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詳細情報 詳細情報について
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- CRID
- 1390282680488905728
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- NII論文ID
- 130003398569
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- NII書誌ID
- AA10690964
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- ISSN
- 21875537
- 02884534
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- NDL書誌ID
- 025143482
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可