Investigation of Nanopore Evolution in Track-Etched Poly(vinylidene fluoride) Membranes

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We investigated the formation of track-etched membranes of poly(vinylidene fluoride) (PVDF), a type of fluoropolymer, in detail, using conductometry. A 25 μm-thick PVDF film was irradiated with a 450 MeV 129Xe or 2.2 GeV 197Au ion beam, and then the latent tracks were etched in a 9 mol dm-3 aqueous potassium hydroxide solution at 80ºC in a conductometric cell. This paper focuses on the theoretical basis of the conductometric method and the apparatus used in our study. Representative results are then given in terms of how the etching kinetics was affected by various experimental conditions including the irradiation parameters and cell voltages applied between the electrodes.

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