Crystal Structures and Magnetic Properties of the System Rh<SUB>1</SUB>Mn<SUB>1&minus;<I>x</I></SUB>Sb<I><SUB>x</SUB></I>

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  • Crystal Structures and Magnetic Properties of the System Rh<SUB>1</SUB>Mn<SUB>1−<I>x</I></SUB>Sb<I><SUB>x</SUB></I>

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Crystal structures and magnetic properties of Rh–Mn–Sb alloys have been investigated by means of X-ray diffraction and magnetic measurements. It has been found that alloys in the composition range of Rh1.00Mn0.66Sb0.34∼Rh1.00Mn0.55Sb0.45 are a solid solution of the face-centered tetragonal L10-type with lattice parameters of 4.200∼4.182 Å and axial ratios of 0.806∼0.829. The typical Rh1.00Mn0.55Sb0.45 alloy has a saturation magnetization of 52.3 emu/g at absolute zero, a magnetic moment of 3.20 μB per Mn atom, a Curie point of 330°K and a paramagnetic Curie point of 286°K. The observed relationship between reciprocal susceptibility and temperature indicates weak ferrimagnetic behavior of this alloy.

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