Calculated Phase Diagram of the Ni–W–B Ternary System

  • Morishita Masao
    Department of Materials Science and Engineering, Faculty of Engineering, Himeji Institute of Technology
  • Koyama Koichiro
    Department of Materials Science and Engineering, Faculty of Engineering, Himeji Institute of Technology
  • Maeda Kouichi
    Former Graduate Student, Himeji Institute of Technology
  • Zhang Guofeng
    Graduate Student, Himeji Institute of Technology

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  • Calculated Phase Diagram of the Ni–W–B Ternary System

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The phase diagram of the Ni–W–B ternary system in the region of less than 50 mol%B was constructed by thermodynamic calculation based on the regular solution approximation. We found three ternary eutectic points and two ternary peritecto-eutectic points as follows:<BR>E1: L(1622 K, 51.0 mol%Ni-31.6 mol%W-17.4 mol%B)=(Ni)+W+NiW2B2<BR>E2: L(1260 K, 71.0 mol%Ni-7.0 mol%W-22.0 mol%B)=(Ni)+Ni3B+NiW2B2<BR>E3: L(1291 K, 65.4 mol%Ni-4.8 mol%W-29.8 mol%B)=Ni2B+Ni3B+NiW2B2<BR>P1: L(2115 K, 23.8 mol%Ni-43.1 mol%W-33.1 mol%B)+WB=W2B+NiW2B2<BR>P2: L(1657 K, 48.9 mol%Ni-33.1 mol%W-18.0 mol%B)+W2B=W+NiW2B2<BR>The calculated phase diagram is expected to be useful for the development of new Ni-based heat-, corrosion- and wear-resistance alloys strengthened by NiW2B2.

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