Mossbauer Study of Iron-Arsenic Compounds

  • Yuzuri Motoyoshi
    Department of Physics, Faculty of Engineering, Yokohama National University
  • Tahara Ryoichi
    Department of Metal Science and Technology, Kyoto University
  • Nakamura Yoji
    Department of Metal Science and Technology, Kyoto University

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  • Mössbauer Study of Iron-Arsenic Compounds
  • Mossbauer Study of Iron Arsenic Compoun

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The magnetic properties of the iron-arsenic compounds Fe2As, FeAs and FeAs2 have been studied with the Mössbauer effect of 57Fe. Fe2As has a Néel temperature of 353K and its magnetic moments align perpendicularly to the c-axis. These results are in agreement with the neutron diffraction measurements. The temperature variations of both the quadrupole interaction and the isomer shift suggest the onset of a second-order magnetic transition at the Néel temperature. FaAs2 shows a doublet associated with quadrupole interactions at 5 K, leading to no magnetic ordering even at low temperatures. The broad absorption spectrum of FeAs at 5 K indicates a magnetic ordering at low temperatures.

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