Optical Investigations of YbCrO<sub>3</sub>. III. Cr<sup>3+</sup>Exciton–Yb<sup>3+</sup>Spin Flip Simultaneous Absorption

  • Kojima Norimichi
    Department of Chemistry, Faculty of Science, Kyoto University
  • Aoyagi Kiyoshi
    Department of Physics, Faculty of Science, Yamagata University
  • Tsushima Kuniro
    Broadcasting Science Research Laboratories of Nippon Hoso Kyokai (Japan Broadcasting Corporation)
  • Tsujikawa Ikuji
    Department of Chemistry, Faculty of Science, Kyoto University
  • Sugano Satoru
    Institute for Solid State Physics, University of Tokyo

書誌事項

タイトル別名
  • Optical Investigations of YbCrO<SUB>3</SUB>. III. Cr<SUP>3+</SUP> Exciton—Yb<SUP>3+</SUP> Spin Flip Simultaneous Absorption

抄録

Absorption spectra corresponding to the 4A2g2Eg transition of Cr3+ in YbCrO3 were studied. In the lowest energy region, R exciton lines with Davydov splitting were observed, and the magnitudes of the inter-sublattice exciton transfers were obtained by the analysis of these spectra. In the shorter wave length side of R exciton lines, a band(R′) of electric dipole character was observed, which has an anomalous shape with a sharp cut-off at the lowest energy side and fine structure. The temperature and magnetic field dependences of R′ band suggest that it corresponds to the simultaneous excitation of a Cr3+ exciton and a spin flip of the Yb3+ ground state. From the analysis of the anomalous shape of R′ band, a negative dispersion of the Cr3+ exciton was found to be −16 cm−1.

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