The Synthesis of 3-Spirooxindole Derivatives. III. Stereospecific Syntheses of rac-N-Methylrhynchophyllane for Stereochemistry of Rhynchophylline and Isorhynchophylline.

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N-Methylrhynchophyllane which is derived from the alkaloids, rhynchophylline and isorhynchophylline, was stereospecifically synthesized and was isolated as two pairs of stereoisomers, thereby establishing the trans-arrangement at C6' and C7' of these alkaloids.

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