Infrared Absorption Spectra of Organic Sulfur Compounds. I. Studies on S-N Stretching Bands of Benzenesulfonamide Derivatives

• 田中 由紀子

• 田中 善正

抄録

The infrared spectra of 44 kinds of benzenesulfonamide derivatives and a few naphthalenesulfonamide derivatives were measured and compared with the benzenesulfonic acid derivatives. The sulfonamide derivatives showed two characteristic bands near 900 cm^-1 and 1090 cm^-1 regions, but the latter didn't show the bands near 900 cm^-1 region. The infrared spectra of deuterated benzenesulfonamide derivatives were examined. In the compound in which nitrogen atom is directly attached to hydrogen, the band near 900 cm^-1 region shifted about 38∼100 cm^-1. However, in case of the compounds where nitrogen atom is not attached to hydrogen, the band near 900 cm^-1 region did not shift on deuteration work. These facts suggest that the band near 900 cm^-1 region can be ascribed to S-N vibration.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 13 (4), 399-405, 1965

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390001204170217984
• NII論文ID: 110003619583
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.13.399
• COI: 1:CAS:528:DyaF2MXktFKntLg%3D
• ISSN: 13475223
• ISSN: 00092363
• PubMed: 14298879
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/13/4/13_4_399/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1966004465
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可