The Reaction of α, β-Unsaturated Cycloalkenones with Azides. I. The Anomalous Products in the Schmidt Reaction

• 三橋 監物

• 野村 敬一

抄録

2-Methyl-(Ia), 2-phenyl-(Ib), 3-methyl-2-cyclohexenone (Xa) and 2-cyclohexenone (Xc) were reacted with equivalent mole of sodium azide in polyphosphoric acid. In all cases, 2-amino-2-cyclohexenone derivatives were yielded as abnormal reaction products. In the cases of Ia and Ib, migration of the methyl and the phenyl group to the position 3 was observed accompanied by the simultaneous introduction of an amino group at the position 2, respectively.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 13 (8), 951-958, 1965

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390001204172646272
• NII論文ID: 110003619686
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.13.951
• ISSN: 13475223
• ISSN: 00092363
• PubMed: 5867837
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/13/8/13_8_951/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1966004416
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可