Studies on Thiohydroxamic Acids and Their Metal Chelates. IV. Reaction of Thiohydroxamic Acids with Metal Ions

• 永田 耕一

• 水上 聰

抄録

Reactivities of thiohydroxamic acids (I) and O-methylthiohydroxamic acids (II) with metal ions are studied. It was found that the behaviors of I resemble those of hydroxamic acids rather than II or other reagents including mercapto group. Namely, I react with Fe(III), Ti(IV), UO₂(II), VO(II) which show the characteristic color reaction with hydroxamic acid, and furthermore I gave the Fe(III) and Cu(II) salts without any changes of the valencies, differing from II. Some properties of the isolated transition metal salts indicated that these salts have probably the chelate structures.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 15 (1), 61-69, 1967

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390282679150584192
• NII論文ID: 110003620003
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.15.61
• ISSN: 13475223
• ISSN: 00092363
• PubMed: 6040979
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/15/1/15_1_61/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1968007974
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可