Studies on Optically Active Amino Acids. XIV. Studies on α-Alkyl-α-amino acids. VII. Determination of Absolute Configuration of Optically Active α-Methylphenylglycine Configuration of Optically Active α-Methylphenylglycine and 1-Methyl-1-phenylpropylamine.

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  • Studies on optically active amino acids-14-Studies on α-alkyl-α-amino acids-7-Determination of absolute configuration of optically active α-methylphenylglycine and 1-methyl-1-phenylpropylamine
  • Studies on optically active amino acids 14 Studies on アルファ-alkyl-アルファ-amino acids 7 Determination of absolute configuration of optically active アルファ-methylphenylglycine and 1-methyl-1-phenylpropylamine

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Abstract

The absolute configuration of (+)-α-methylphenylglycine was proved to be S series by the chemical correlation with R (-)-isovaline. Chemical scheme employed was shown in Chart 1. Moreover, in the course of the chemical correlation, the absolute configuration of (+)-1-methyl-1-phenylpropylamine was also proved to be R series. Preliminary experiments using racemic compounds were also described.

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