Osmium Tetroxide Oxidation of Hopa-15, 17(21)-diene, Dehydrozeorinin, and Hop-17(21)-ene

• 津田 喜典

• 礒部 公明

抄録

The structures of the diol and the conjugated ketone obtained from the osmium tetroxide oxidation of hopa-15, 17(21)-dienes (I) were now revised and correctly assigned as IV and V, respectively, the former being obtained by lithium aluminum hydride decomposition and the latter by hydrogen sulfide decomposition of the intermediate osmate. Hop-17(21)-ene (VI) was also found to give the seco-diketone (VIII) in lesser yield. A probable mechanism for the formation of the seco-diketones was also discussed.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 15 (6), 797-801, 1967

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390282679150365824
• NII論文ID: 110003620236
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.15.797
• ISSN: 13475223
• ISSN: 00092363
• NDL書誌ID: 8509109
• PubMed: 6076789
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8509109
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/15/6/15_6_797/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1969055751
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可