Chemical Studies on the Oriental Plant Drugs. XXX. Sapogenins of the Roots of Platycodon grandiflorum A. DE CANDOLLE. (1). Isolation of the Sapogenins and the Stereochemistry of Polygalacic Acid

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From the saponins of the roots of Platycodon grandiflorum A. DC. polygalacic acid and a new triterpene acid, platycodigenin, were obtained as main sapogenins. The structure of polygalacic acid formerly proposed by Rondest et al., was amended to be 2β, 3β, 16α, 23-tetrahydroxy-olean-12-en-28-oic acid.

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