Studies on indenopyridine derivatives and related compounds. I. Syntheses and sterechemistries of 1-substituted 1,2,3,4,4a,9a-hexahydro-4-hydroxy-9H-indeno(2,1-b)pyridines and related compounds.

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Reduction of the vinylogous lactam (V or VI), either chemically or catalytically, afforded the epimeric mixture of amino alcohols accompanied the dehydration products, and these stereostructure were assigned as B/C-cis stable form of 1-substituted 1, 2, 3, 4, 4a, 9a-hexahydro-4-hydroxy-9H-indeno [2, 1-b] pyridines. Oxidation reaction of these amino alcohols were attempted.

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