Studies on organic fluorine compounds. XVII. Reaction of benzotrifluoride derivatives with sodium amide.

• 小林 義郎

• 熊懐 稜丸

• 榛沢 雄二

• 三村 雅隆

抄録

Reaction of benzotrifluoride derivatives with sodium amide was examined. o-Nitro-and p-amino-benzotrifluoride gave the corresponding benzonitriles. m-Nitrobenzotrifluoride gave 3, 3'-bis (trifluoromethyl) azoxybenzene and 3, 8-bis (trifluoromethyl) benzo [c]-cinnoline 5-oxide. p-Nitrobenzotrifluoride gave p-nitrobenzonitrile, 2, 2'-dinitro-5, 5'-bis (trifluoromethyl) biphenyl and 4, 4'-dicyanoazoxybenzene. Reaction mechanism for each product is proposed.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 23 (3), 636-639, 1975

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390282679150418688
• NII論文ID: 110003621910
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.23.636
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/23/3/23_3_636/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1975084626
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可