The Stevens rearrangement of quarternary isoquinolinium salts.

• 加納 慎蔵

• 横松 力

• 小野 敏広

• 高萩 洋子

• 渋谷 皓

抄録

The reaction of 1, 2, 3, 4-tetrahydro-6, 7-dimethoxy-1-(3, 4-methylenedioxyphenyl)-2, 2-dimethylisoquinolinium iodide (3) with dimsylsodium afforded the 1-methyl-1-phenylisoquinoline (4) and the N, N-dimethyldiphenylmethylamine (5). Similar reaction using the berbine methiodide (8), (16), (17) yielded the corresponding ochotensine type 1-spirobenzylisoquinolines (9), (14), and (15), respectively. The homoberbine (20) also gave the 1-spiroisoquinoline (22), however, the reaction of the homoberbine (23) with dimsylsodium yielded the tetrahydro-13, 14-trans-dibenz [c, g] azacycloundecine (28).

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 25 (10), 2510-2515, 1977

  公益社団法人 日本薬学会

キーワード

• dibenz [c, g] azacycloundecine

詳細情報

• CRID: 1390001204170359808
• NII論文ID: 110003622223
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.25.2510
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/25/10/25_10_2510/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1978106911
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可