Stereochemistry of quinolizidines. III. Carbon-13 magnetic resonance spectra of benzo[a]quinolizidines.

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Stereochemistry of benzo [α] quinolizidine derivatives (I-VIb) were examined from C-13 magnetic resonance chemical shifts, and C-6 and C-7 shifts of these compounds were found to be reliable as the indications of favoured conformations-trans, cis "a" or cis "b". This treatment is also available for the conformational analyses of tetrahydroproto-berberine type alkaloids.

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