Synthesis of the dodecapeptide amide corresponding to the entire amino acid sequence of granuliberin-R, a new frog skin peptide from Rana rugosa.

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Amino acid sequence of a new frog skin peptide named granuliberin-R, H-Phe-Gly-Phe-Leu-Pro-Ile-Tyr-Arg-Arg-Pro-Ala-Ser-NH2, was assessed by two conventional ways of synthesis ; the one by the methanesulphonic acid procedure and the other by the catalytic hydrogenation procedure at the final deprotection steps.

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