Reaction of N-methoxypyridinium salt with nitroalkanes. Additive cleavage reaction of pyridine nucleus.

• 高山 浩明

• 岡本 敏彦

抄録

The reactions of N-methoxypyridinium iodide with nitromethane, nitroethane, and 1-nitropropane in the presence of sodium ethoxide in anhydrous ethanol afforded 1-methoxyimino-6-nitrohexa-2, 4-diene, 1-methoxyimino-6-aci-nitrohepta-2, 4-diene, and 1-methoxyimini-6-aci-nitroocta-2, 4-diene, respectively. The spectral behaviors of these products were discussed in relation to the nitro-acinitro prototropy and the assumed reaction mechanism was also offered.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 26 (8), 2422-2427, 1978

  公益社団法人 日本薬学会

キーワード

• conjugated polyene

詳細情報

• CRID: 1390001204170572672
• NII論文ID: 110003623309
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.26.2422
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/26/8/26_8_2422/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1979093968
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可